Process for the production of tertiary olefin

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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C07C 120, C07C 1108

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active

043439594

ABSTRACT:
A tertiary olefin is produced by making a gaseous tertiary ether usually represented by the following general formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are alkyl groups each having 1-4 carbon atoms which may be same or different each other and R.sup.4 is an alkyl group having 1-3 carbon atoms, contact a catalyst obtained by calcining a silica-alumina compound at 700.degree.-1100.degree. C. in order to carry out cracking of the tertiary ether.

REFERENCES:
patent: 3170000 (1965-02-01), Verdol
patent: 4065507 (1977-12-01), Hardman et al.
patent: 4254296 (1981-03-01), Manara et al.
Chem. Abs. 59, 11232f (1963).
Chem. Abs. 92, 170022(a) 1980.
Derwent, 15070W/09 JH 909H-602.
Derwent, 01935C/02 DT 2924-869.

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