Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge
Patent
1977-10-31
1979-08-21
Sebastian, Leland A.
Chemistry: electrical and wave energy
Processes and products
Electrostatic field or electrical discharge
204158HA, B07J 110
Patent
active
041652681
ABSTRACT:
A process for the production of benzal bromides which contain an electrophilic substituent in the ortho- and/or para-position of the formula (Ia), or of mixtures thereof with the corresponding benzyl bromides of the formula (Ib), ##STR1## IN WHICH R represents an electrophilic substituent in the ortho- and/or para position, by treating correspondingly substituted toluenes with elementary bromine under irradiation with visible light in a two-phase system which consists of an aqueous and an organic phase, which process comprises carrying out the reaction in the presence of a base.
REFERENCES:
patent: 3993704 (1976-11-01), Marsh et al.
Gosteli Jacques
Marti Franz
Somlo Tibor
Almaula Prabodh I.
Ciba-Geigy AG
Sebastian Leland A.
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