Process for the production of shaped articles of niobium or...

Electrolysis: processes – compositions used therein – and methods – Electrolytic erosion of a workpiece for shape or surface... – Using mask

Reexamination Certificate

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C205S684000

Reexamination Certificate

active

07090763

ABSTRACT:
Process for the production of shaped articles of niobium or tantalum by electrochemical etching of a niobium or tantalum sheet covered by a structured photoresist mask in an aqueous solution containing hydrofluoric acid, the etching being effected under electrochemical conditions under which strong noise is superposed on the etching current and the etching solution contains a water-soluble polymer.

REFERENCES:
patent: 2775553 (1956-12-01), Kahan
patent: 3314867 (1967-04-01), Gore et al.
patent: 3689288 (1972-09-01), Diepers et al.
patent: 4266008 (1981-05-01), Kampwirth et al.
patent: 5690807 (1997-11-01), Clark et al.
patent: 2002/0088709 (2002-07-01), Hongo et al.
patent: 2002/0108861 (2002-08-01), Emesh et al.
patent: 2003/0087528 (2003-05-01), Kruwinus et al.
patent: 56-81680 (1981-07-01), None
patent: 662624 (1979-05-01), None
patent: 876808 (1979-11-01), None
Red'kin et al, Electrochemical Etching of a Niobium Film through a Tin Nanomask Formed by AFM Tip-Induced Local Oxidation, Mar. 2003, MAIK Nauka Interperiodica, vol. 32, No. 2, pp. 88-90.
Petzow, Metallographic Etching, 1999, ASM International, pp. 80-89.
Jenny et al., Electrolytic Etching of Dense Tantalum, 1961, Journal of the Electrochemical Society, vol. 108, pp. 442-445.
Shtan'ko et al., Influence of Anodic Polarization on the Process of Anodic Dissolution of Tantalum, 1978, Vopr. Khim. Tekhnol., 80, p. 7-10.
M. Köhler in Ätzverfahren für die Mikrotechnik [Etching methods for microengineering], Wiley-VCH-Verlag (month unavailable) 1998, p. 306 , “Nb—Niob”.
G. Petzow, in Metallographisches, keramographisches, plastographisches Ätzen [Metallographic, Ceramographic, plastographic etching], Gebr. Borntraeger Verlag, 6th edition, (month unavailable) 1994, p. 99, “Refraktämetalle”.
Database WPI Section Ch, Week 198005 Derwent Publications Ltd., London, GB; XP002274520 & SU 662 624 A (As Latv Inorg Chem) 18. May 18, 1979.
Database CA 'Online! Chemical Abstracts Service, Columbus, Ohio, US; Kadaner, L. I. et al: “Solution for electrochemical polishing of niobium articles” XP002274518 gefunden im STN Database accession No. 96:76531 CA & Database WPI Section Ch, Week 198235 Derwent Publications Ltd., London, GB; AN 1982-74156E XP002274521 & SU 876 808 A (Khark Pedagogy Inst) 2. Nov. 2, 1981.
Database CA 'Online! Chemical Abstracts Service, Columbus, Ohio, US; Shtan'ko, V.M. et al: “Effect of anodic polarization on the anodic dissolution of tantalum” XP002274519 gefunden im STN Database accession No. 89:206298 Ca & Voprosy Khimii I Khimicheskoi Tekhnologii (1978), 50, 7-10, 1978.

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