Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1973-09-24
1976-09-07
Thomas, Jr., James O.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260660, C07C 1702
Patent
active
039794709
ABSTRACT:
Primary normal monochloroparaffins are produced in high yields in a chlorination process of normal paraffins by the recycling technique of the present invention. By the recycling of secondary and nonprimary monochloroparaffin to the chlorination zone and the treatment of the polychlorinated compounds formed in the chlorination to form the primary normal monochloroparaffins and a recycle stream of paraffin and nonprimary monochloroparaffin, normal paraffins may be converted essentially completely to the desired primary normal monochloroparaffins. In a specific aspect of the present invention, alpha, omega-dichloroparaffins may be recovered if desired.
REFERENCES:
patent: 2886605 (1959-05-01), McClure et al.
patent: 3278614 (1966-10-01), Michel et al.
patent: 3426086 (1969-02-01), Gray et al.
patent: 3505418 (1970-04-01), Jubin
Groggins, Unit Processes in Organic Synthesis, McGraw-Hill Co. Inc., (1952), pp. 194-203.
Carter Brian H.
Chute Robert E.
Firnhaber Bernhard E.
Pullman Incorporated
Reamer James H.
Thomas, Jr. James O.
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