Process for the production of porous electrodes

Chemistry: electrical and wave energy – Processes and products

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204 381, C25D 500

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active

048571539

ABSTRACT:
Porous electrodes are obtained by a method in which a layer of a powder mixture comprising (a) finely divided carbonyl metal having a low bulk density and high frictional resistance and (b) a pulverulent component which is catalytically active or can be activated by alkali treatment, in an a/b ratio of about 3:1 to 1:3, is applied by rolling to one or both sides of a framework-forming metallic substrate having adhesion-promoting surface roughness, and said layer is consolidated by electrodeposition of metal, after which activation is finally effected if necessary. Superficial oxidation of the powder particles, which decreases from the outer surface of the layer toward the support and gradually dissolves in the electroplating bath, promotes extensive consolidation of the layer by electrodeposition.

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patent: 4302322 (1981-11-01), Oda et al.
patent: 4584065 (1986-04-01), Divisek et al.
Justi et al., "Kalte Verbrennung," Franz Steiner Verlag GmbH, Wiesbaden 1, pp. 8, 110.
Veziroglu et al., (editors), "Hydrogen Energy Progress V," Proceedings of the 5th World Hydrogen Energy Conference, Toronoto, Canada, Jul. 15-20, 1984, p. 933.
Mueller et al., "Raney-Nickel-beschichtete Elektroden," Chem.-Ing.-Tech. 52, 1980, Nr. 5, pp. 435-436.
INCO-Nickelpulver, Eigenschaften und Verwendung, pp. 3-9.

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