Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1995-07-27
1996-08-06
Teskin, Fred
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526 74, 526 89, 526135, 526138, 526185, 526189, 526221, 526237, 526339, 5263487, 526941, C08F 414, C08F 416, C08F 1010
Patent
active
055434797
ABSTRACT:
Polyisoolefins are produced according to the invention by polymerizing isoolefins having 4 to 16 carbon atoms, optionally with conjugated diolefins having 4 to 6 carbon atoms and/or cationically polymerizable, mono- or polyunsaturated, organic compounds having 4 to 16 carbon atoms in the presence of mixtures of carbon dioxide and linear, branched and/or cyclic C.sub.4 -C.sub.8 alkanes and in the presence of catalysts at temperatures of -70.degree. C. to +20.degree. C. and pressures of 1 to 70 bar, wherein the weight ratio of carbon dioxide to alkanes is 10:90 to 90:10.
The process according to the invention largely prevents the formation of fouling on the reactor walls, so ensuring better removal of heat. Moreover, in accordance with the process according to the invention, the polyisoolefins obtained may be directly chemically modified once the carbon dioxide has been removed.
REFERENCES:
patent: 2456354 (1948-12-01), Young
patent: 3522228 (1970-07-01), Fukui et al.
patent: 5376744 (1994-12-01), Kennedy et al.
Orbit Abstract of EP 0 025 530 (Mar. 25, 1981).
Baade Wolfgang
Heinrich Roland
Langstein Gerhard
Mulder Thomas
Puskas Judit
Bayer AG
Teskin Fred
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