Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...
Patent
1996-04-05
1998-09-22
Caldarola, Glenn
Chemistry of hydrocarbon compounds
Aromatic compound synthesis
By condensation of entire molecules or entire hydrocarbyl...
585446, C07C 266
Patent
active
058116133
ABSTRACT:
A selective, simple and efficient process for single step alkylation of ethylbenzene with ethanol, in the presence of catalytically effective amount of pore size controlled and preconditioned gallo aluminosilicate zeolite is disclosed. The process comprises subjecting a feed mixture of ethylbenzene, ethanol and optionally one or more of the reaction product/byproduct in contact with the catalyst under a chosen set of conditions. The product para-diethylbenzene can be recovered directly from the reactor effluent, by simple distillation, avoiding complicated separation processes, with a high purity sufficient for commercial application.
REFERENCES:
patent: 4117026 (1978-09-01), Haag et al.
patent: 4386230 (1983-05-01), Hogan et al.
patent: 4677240 (1987-06-01), Carlson et al.
patent: 4973781 (1990-11-01), Valyocsik et al.
Bhat Yajnavalkya Subray
Das Jagannath
Halgeri Anand Bhimrao
Caldarola Glenn
Dang Thuan D.
Indian Petrochemicals Corporation Limited
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