Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1979-03-28
1980-07-01
Sweed, Helen M. S.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
C07F 722
Patent
active
042105951
ABSTRACT:
The direct reaction of metallic tin with an .alpha.,.beta.-unsaturated nitrile, hydrogen chloride, hydrogen bromide or hydrogen iodide in the presence of an alcohol yields diorgano-tin dihalides with an iminoester function in the organo groups. This iminoester function can be converted with mercaptans into the corresponding iminothioester function. The novel diorgano-tin dihalides of the formula ##STR1## wherein X represents a chlorine, bromine or iodine atom,
REFERENCES:
patent: 3412122 (1968-11-01), Considine et al.
patent: 3440255 (1969-04-01), Matsuda
patent: 3607893 (1971-09-01), Reifenberg
patent: 4105684 (1978-08-01), Hutton et al.
patent: 4130573 (1978-12-01), Hutton et al.
Rappoport, The Chemistry of the Cyano Group Interscience, pp. 264-265 (1970).
Wehner Hermann W.
Wirth Hermann O.
Ciba-Geigy Corporation
Hall Luther A. R.
Sweed Helen M. S.
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