Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Reexamination Certificate
2004-10-15
2008-09-23
Witherspoon, Sikarl A (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
C549S295000, C549S302000, C568S852000
Reexamination Certificate
active
07427684
ABSTRACT:
A homogeneous process for the hydrogenation of dicarboxylic acid and/or derivative thereof with an amine in the presence of a catalyst comprising: (a) ruthenium or osmium; and (b) an organic phosphine; and wherein the hydrogenation is carried out in the presence of water.
REFERENCES:
patent: 2351939 (1944-06-01), Drossbach et al.
patent: 2843600 (1958-07-01), McKeever
patent: 3080377 (1963-03-01), Liao
patent: 3109005 (1963-10-01), Lidov
patent: 3637743 (1972-01-01), Prince
patent: 3957827 (1976-05-01), Lyons
patent: 4263175 (1981-04-01), Pesa et al.
patent: 4356124 (1982-10-01), Pesa et al.
patent: 4485245 (1984-11-01), Hsu et al.
patent: 4485246 (1984-11-01), Lyons
patent: 4892955 (1990-01-01), Wada et al.
patent: 4931573 (1990-06-01), Wada et al.
patent: 5021589 (1991-06-01), Wada et al.
patent: 5047561 (1991-09-01), Miyazawa et al.
patent: 5077442 (1991-12-01), Hara et al.
patent: 5079372 (1992-01-01), Wada et al.
patent: 5434273 (1995-07-01), Weyer et al.
patent: 5580991 (1996-12-01), Sugiyama et al.
patent: 5912358 (1999-06-01), Frohn et al.
patent: 6008375 (1999-12-01), Bergfeld et al.
patent: 976939 (1964-12-01), None
patent: 2 055 798 (1981-03-01), None
patent: 02-075716 (1990-03-01), None
patent: 02121976 (1990-05-01), None
patent: 02200680 (1990-08-01), None
patent: 02207081 (1990-08-01), None
patent: 02233674 (1990-09-01), None
patent: 02235880 (1990-09-01), None
patent: 03074377 (1991-03-01), None
patent: 03083974 (1991-04-01), None
patent: 03112973 (1991-05-01), None
patent: 03141273 (1991-06-01), None
patent: 03204870 (1991-09-01), None
patent: 04091085 (1992-03-01), None
patent: 04217636 (1992-08-01), None
patent: 06107654 (1994-04-01), None
patent: 06172338 (1994-06-01), None
patent: 07033756 (1995-02-01), None
patent: 07082260 (1995-03-01), None
patent: WO 96/23803 (1996-08-01), None
patent: WO 02/102772 (2002-12-01), None
patent: WO 03/093208 (2003-11-01), None
H. Inagaki, S. Nishimura, Y. Hara, K. Wada, “Hydrogenation Reaction of Carbonyl Compounds Catalyzed by Cationic Ruthenium Complexes,” Science and Technology in Catalysis 1994, pp. 327-330.
Y. Hara, K. Wada, “Hydrogenation Reaction of Carboxylic Anhydrides Catalyzed by a New and Highly Active Cationic Ruthenium Complex,” Chemistry Letters 1991, pp. 553-554.
R.A. Grey, G.P. Pez, A. Wallo, “Anionic Metal Hydride Catalysts. 2. Application to the Hydrogenation of Ketones, Aldehydes, Carboxylic Acid Esters, and Nitriles,” Journal of the American Chemical Society 1981, No. 103, pp. 7536-7542.
U. Matteoli, G. Menchi, M. Bianchi, F. Piacenti, “Homogeneous Catalytic Hydrogenation of the Esters of Bicarboxylic Acids -Part III. EthyleneGlycol from Dimethyl Oxalate,” Journal of Molecular Catalysis, No. 44, 1988, pp. 347-355.
U. Matteoli, G. Menchi, M. Bianchi, F. Piacenti, S, Ianelli, M. Nardelli, “Structure and Catalytic Activity of Phosphine-substituted Ruthenium Carbonyl Carboxylates,” Journal of Organometallic Chemistry, vol. 498, 1995, pp. 177-186.
H. Teunissen, C.J. Elsevier, “Ruthenium Catalysed Hydrogenation of Dimethyl Oxalate to Ethylene Glycol,” Chemical Communications, 1997, pp. 667-668.
H.T. Teunissen, C.J. Elsevier, Homogeneous Ruthenium Catalyzed Hydrogenation of Esters to Alcohols, Chemical Communications, 1998, pp. 1367-1368.
Crabtree Simon Peter
Sharif Mohammed
Tyers Derek Vincent
Davy Process Technology Limited
McDonnell Boehnen & Hulbert & Berghoff LLP
Witherspoon Sikarl A
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