Process for the production of ethers

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568601, 568607, 568608, 568609, 568610, 568613, 568614, C07C 4102

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043919944

ABSTRACT:
Oxyalkylene group of an alkylene oxide is inserted into a chain-type ether compound having at least one lower alkyl group by reacting the latter with the alkylene oxide in the presence of a catalyst prepared by mixing boron trifluoride and/or stannic chloride with an active-hydrogen compound exemplified by water or a lower aliphatic alcohol. The reaction results reduced formation of by-product dimer of the alkylene oxide even under an increased charging ratio of the alkylene oxide to the chain-type ether.

REFERENCES:
patent: 4146736 (1979-03-01), Scheffel et al.

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