Process for the production of esters exhibiting nonlinear optica

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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526312, 560 55, 560 85, 560103, 560121, 560123, 560124, 560182, 560205, 560231, C07C 6952

Patent

active

049979779

ABSTRACT:
This invention provides multistep process embodiments for the production of novel esters which exhibit nonlinear optical response.
A process embodiment is illustrated by the reaction of a Schiff base with a substituted acetic acid to form a stilbene alcohol intermediate: ##STR1## The stilbene alcohol intermediate is decarboxylated, and then is esterified in the presence of a pyridine type catalyst to provide an ester with a conjugated structure.

REFERENCES:
patent: 4540743 (1985-09-01), Schulz et al.
patent: 4808332 (1989-02-01), Demartino et al.
patent: 4810338 (1989-03-01), DeMartino et al.

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