Process for the production of epoxides

Details Process for the production of epoxides Process for the production of epoxides

1988-01-27

1989-11-21

Raymond, Richard L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30112

Patent

active

048824429

ABSTRACT:
Process for the production of epoxides by reaction of one mol equivalent of the corresponding olefins with 1 to 2.6 mols equivalent aliphatic percarboxylic acids with 2-4 C atoms containing at least one strong acid, wherein the strong acid in the percarboxylic acid mixture is neutralized with an at least equivalent amount of an inorganic base and thereafter the percarboxylic acid mixture is combined with a reaction mixture containing the olefin, about 0.5 to about 0.74 equivalents acid-binding agent with reference to the amount of total carboxylic acid present in the percarboxylic acid mixture and, if necessary, solvent.

REFERENCES:
patent: 2838524 (1958-06-01), Wilson
patent: 2875178 (1959-02-01), Greenspan et al.
patent: 2899446 (1959-08-01), Marks
Korach et al., Jour. Am. Chem. Soc., vol. 82 (1960) pp. 4328-4330.

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