Process for the production of diaryl iodonium compounds

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Preparing organic compound

Reexamination Certificate

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C205S424000, C205S426000, C205S427000, C205S438000, C205S444000, C205S456000, C205S459000

Reexamination Certificate

active

07052593

ABSTRACT:
The present invention provides an electrochemical method for producing diaryl iodonium compounds wherein application of an electric current to an electrochemical cell containing a reaction mixture composed of a solvent, an iodoaryl compound and an electrolyte forms an oxidizing agent in situ. In this first step, the oxidizing agent is subsequently converted into a stable oxidized iodoaryl intermediate, typically an iodosyl compound. The electric potential is removed and in a second step a target aryl compound is introduced to the reaction mixture to react with the oxidized iodoaryl intermediate to form a diaryl iodonium compound.

REFERENCES:
patent: 3885036 (1975-05-01), Moyle
patent: 4513137 (1985-04-01), Koser et al.
patent: 4759833 (1988-07-01), Lentz et al.
patent: 5277767 (1994-01-01), Cushman et al.
patent: 6419814 (2002-07-01), Pletcher et al.
patent: 6620305 (2003-09-01), Cornell et al.

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