Process for the production of cycloolefin random copolymer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526126, 526127, 526133, 526134, 526151, 526153, 526170, 526281, 526282, 526943, C08F 206, C08F23208

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056504713

ABSTRACT:
There is provided a process for the production of a cycloolefin copolymer which comprises copolymerizing an .alpha.-olefin having 2 or more carbon atoms and a specific cycloolefin in the presence of a specific metallocene type catalyst in a solvent mixture of a hydrocarbon solvent having a solubility parameter (value of .delta.) of 7.7 [(cal/cm.sup.3).sup.1/2 ] or more and a hydrocarbon solvent having a solubility parameter (value of .delta.) of 7.5 [(cal/cm.sup.3).sup.1/2 ] or less as a polymerization solvent. A cycloolefin copolymer having a high molecular weight can be produced in a high concentration by this process at a high yield.

REFERENCES:
patent: 5003019 (1991-03-01), Ishimaru et al.
patent: 5008356 (1991-04-01), Ishimaru et al.
patent: 5142007 (1992-08-01), Sagane et al.

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