Process for the production of certain 2,3-dihydro-benzofuran der

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D30786

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048165921

ABSTRACT:
A process for the production of benzofuran derivatives having the general formula, ##STR1## wherein R is alkyl, in particular of 2,3-dihydro-2,2-dimethyl benzofuran-7-ol, starting from pyrocatechol ethers in one step operation.
The process essentially consists of heating a solution of pyrocatechol ether in an inert organic solvent in the presence of a catalyst comprising metals of 3.degree. and 4.degree. group of the Periodic System in form of carboxylates or of modified zeolites.
The products are known intermediates for the production of insecticides.

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Bartz et al, J.A.C.S., vol. 57, pp. 371-376 (1935).
Olah, Friedel-Crafts & Related Reactions, vol. 1, pp. 25-27, 202, 203, 258, 259, 289, and 307 (1963).
Mustafa, Benzofurans, Wiley Publishers, pp. 144 and 145 (1974).

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