Process for the production of carboxylic acid esters by catalyti

Details Process for the production of carboxylic acid esters by catalyti Process for the production of carboxylic acid esters by catalyti

1977-03-25

1978-11-21

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

260603C, 562538, 568594, C07C 6740

Patent

active

041267486

ABSTRACT:
In an improved process for the production of carboxylic acid esters by catalytic oxidation of alcohols in the liquid phase, primary alcohols of 1-4 carbon atoms are oxidized with molecular oxygen at temperatures of about 100.degree.-250.degree. C. in the presence of catalytic amounts of a compound of Co, Mn, Cr, or Fe, and an acid having a first dissociation constant K.sub.1 greater than 10.sup.-3, dissolved in the reaction mixture.

REFERENCES:
patent: 2287803 (1942-06-01), Hull

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