Process for the production of carboxylic acid esters

Details Process for the production of carboxylic acid esters Process for the production of carboxylic acid esters

1981-12-11

1984-08-14

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

2604109R, 560180, 560190, 560205, 560226, C07C 6704

Patent

active

044658524

ABSTRACT:
A process for producing carboxylic acid esters by reacting an olefin and a carboxylic acid in the presence of a crystalline metallosilicate catalyst. The catalyst has a mole ratio of silica to metal oxide of at least 12. The metal of the metal oxide is an element selected from the group consisting of the elements belonging to Groups III, IV, V, VI B, and VIII of the Periodic Table. The catalyst is preferably zeolitic, for example zeolitic aluminosilicate. The process is particularly effective when reacting relatively inactive olefins such as methylene and propylene.

REFERENCES:
patent: 3076840 (1963-02-01), Brandenburg
patent: 3085108 (1963-04-01), Stepanek
patent: 3096365 (1963-07-01), Heisler
patent: 3492341 (1970-01-01), Trevillyan
patent: 4365084 (1982-12-01), Young
Rabo, "Zeolite Chemistry and Catalysis" (ACS Monograph 171), pp. 615-618, (1976).

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