Process for the production of bromo substituted tetrahydrofuran

Details Process for the production of bromo substituted tetrahydrofuran Process for the production of bromo substituted tetrahydrofuran

1975-07-16

1977-05-10

Phillips, Delbert R.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603457, 260515M, 260607AR, 260607AL, C07D30902

Patent

active

040228045

ABSTRACT:
A process for the manufacture of .beta.-bromoalkylsulfones and .beta.-bromoalkenylsulfones by addition reaction of sulfonic acid bromides with olefins or acetylenes in the presence of hydroperoxide and, optionally, of metal salts. Starting materials for further syntheses and for biologically active compounds may be obtained by subsequent dehydrobromination of the addition products.

REFERENCES:
patent: 2573580 (1951-10-01), Ladd
J. Org. Chem. vol. 39 No. 26 pp. 3867-3870 (1974).
Tet. (1965) vol. 21 pp. 2743-2747.

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