Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1974-03-08
1976-07-20
Mars, Howard T.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260497A, 203 71, 203 84, C07C 2900
Patent
active
039707130
ABSTRACT:
Allyl alcohol is produced in simple and economical fashion from propylene and oxygen by reacting propylene, oxygen and acetic acid over a palladium-containing catalyst in the presence of water; condensing the reaction product to form a condensate containing allyl acetate, acetic acid and water; treating the condensate with an acid catalyst and separating the resulting product by distillation into a head product consisting essentially of an allyl acetate/allyl alcohol/water azeotrope and into a sump product consisting essentially of acetic acid, allyl alcohol and water; recycling the head product to the acid catalyst stage; separating the sump product in a second distillation into an allyl alcohol/water head product and into a second sump product consisting essentially of acetic acid and water and recycling this sump product to the initial reaction.
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Engelhard Bruno
Grolig Johann
Martin Manfred
Reissinger Karl-Hermann
Scharfe Gerhard
Bayer Aktiengesellschaft
Mars Howard T.
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