Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1975-02-12
1977-07-19
Thomas, Jr., James O.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260600R, 260601R, 260602, 260598, 260599, 260601H, 2603475, C07C 6300, C07C 4752, C07C 4754
Patent
active
040368777
ABSTRACT:
The invention relates to a process for the preparation of aldehydes by hydrogenating carboxylic chlorides of the general formula RCOCl, wherein R stands for alkyl, isoalkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl, aromatic, heterocyclic or substituted heterocyclic group, the substituents being alkyl, halogen, hydroxy, alkoxy, carboxyl, carbonyl and nitro groups wherein the hydrogenation is carried out in the presence of an alloy catalyst comprising at least one element of the platinum group and at least one element of the groups IB and IIB of the periodic system.
The invention renders possible the production of aldehydes in a fair yield and at an adequate selectivity.
REFERENCES:
patent: 3517066 (1970-06-01), Gurien et al.
Karpova et al., Chem. Abstracts, vol. 56, 55e, 1962.
Rosenmund, K. W., Berichte, vol. 51, pp. 585-593, 1918.
Mathe Tibor
Petro Jozsef
Tungler Antal
Budapesti Muszaki Egyetem
Lone W. B.
Thomas, Jr. James O.
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