Process for the production of a polymer comprising monomeric...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S160000, C526S165000, C526S336000, C502S103000, C502S152000, C502S155000

Reexamination Certificate

active

07829645

ABSTRACT:
The invention relates to a process for the preparation of a polymer comprising monomeric units of ethylene, an α-olefin and a vinyl norbornene applying as a catalyst system: a. a bridged or an group 4 metal containing an unbridged catalyst having a single cyclopentadienyl ligand and a mono substituted nitrogen ligand, wherein said catalyst is defined by the formula (I): b. an aluminoxane activating compound, c. 0-0.20 mol per mol of the catalyst of a further activating compound,wherein Y is a substituted carbon or nitrogen atom. The invention further relates to a polymer obtainable with the process of the invention.

REFERENCES:
patent: 6486276 (2002-11-01), Wang et al.
patent: 6583082 (2003-06-01), Hoang et al.
patent: 1 162 214 (2001-12-01), None
patent: WO 97/38019 (1997-10-01), None
patent: WO 00/11048 (2000-03-01), None
Winfried P. Kretschmer et al; “A highly efficient titanium-based olefin polymerization catalyst with a monoanionic iminoimidazolidide .pi.-donor ancillary ligand”; Chemical Communications (Cambridge, United Kingdom), (6), pp. 608-609, 2002.
Harri Lasarov et al; “Ethylene-norbornene terpolymerization with 5-vinyl-2-norbornene using single-site catalysts”; Macromolecular Rapid Communications, 22(6), pp. 434-438, 2001.

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