Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1977-08-17
1979-02-27
Coughlan, Jr., Paul M.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
C07D24920
Patent
active
041419030
ABSTRACT:
A process for the production of 2-aryl-2H-benzotriazoles comprises reducing and cyclizing the corresponding o-nitroazobenzenes with carbon monoxide at a temperature in the range of about 20.degree. C. to about 150.degree. C. and at a pressure in the range of about 15 psia (1 atmosphere) to about 1000 psia (66 atmospheres) in an alkaline medium at a pH over 10 in the presence of a copper-amine complex catalyst. High yields of pure product are obtained with a concomitant reduction of undesired by-products and a reduction in effluent pollution problems.
REFERENCES:
patent: 3978074 (1976-08-01), Jancis
Ciba-Geigy Corporation
Coughlan, Jr. Paul M.
Hall Luther A. R.
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