Process for the production of 2,6-diisopropylnaphthalene

Chemistry of hydrocarbon compounds – Plural serial diverse syntheses – To produce aromatic

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585323, 585449, 585450, 585456, 585466, 585474, 585467, 585475, 585828, C07C 400, C07C 264, C07C 266, C07C 712

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active

049508245

ABSTRACT:
A process for the production of 2,6-diisopropylnaphthalene is disclosed wherein an isopropylation reaction mixture containing isopropylated naphthalenes is subjected to transalkylation with a triisopropylnaphthalene-containing mixture to obtain a mixture containing mono-, di- and tri-isopropylnaphthalenes which is then separated into a first fraction containing monisopropylnaphthalenes, a second fraction containing diisopropylnaphthalenes and a third fraction containing triisopropylnaphthalenes. The first and third fractions are recycled to the above system, while the second fraction is subjected to separation treatments for the recovery of 2,6-diisopropylnaphthalene. The second fraction from which 2,6-diisopropylnaphthalene has been removed is subjected to transalkylation with naphthalene to obtain a monoisopropylnaphthalene-rich mixture which is to be fed to the isopropylation step.

REFERENCES:
patent: 2592587 (1952-04-01), Nickels
patent: 2985589 (1961-05-01), Broughton et al.

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