Process for the production of 17.alpha.-ethynyl-17.beta.-hydroxy

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07J 100

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047190540

ABSTRACT:
A process and novel starting materials for the production of 17.alpha.-ethynyl-17.beta.-hydroxy-18-methyl-4,15-estradien-3-one of Formula I ##STR1## are disclosed. Novel 17-ketone starting materials have the Formula II ##STR2## wherein R is an alkyl residue of 1-3 carbon atoms and ##STR3## is the grouping ##STR4## wherein R' is an acyl group of up to 10 carbon atoms.

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Alberto Ercoli et al., An Improved Method of Preparing Testosterone, Dihydrotestosterone and Some of their Esters, J. Am. Chem. Soc. 75 (1953).

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