Process for the preparation of zirconia

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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423608, B01J 2106

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active

054478987

ABSTRACT:
A process for the preparation of a zirconia precursor comprises contacting a solution of an acidic zirconium compound with a solution of a basic zirconium compound to form a gel. A shapable dough may be formed by rendering the zirconia precursor shapable, for example by drying the zirconia precursor or combining the zirconia precursor with a solid filler. The shapable dough may be shaped, for example by extrusion, to form a shaped zirconia precursor, which in turn may be dried and calcined to form shaped zirconia particles. The shapable dough may be prepared so as to comprise a source for a catalytically active component, in which case the shaped zirconia particles may be used directly as a catalyst. A source of a catalytically active component may be deposited on the shaped zirconia particles to yield a finished catalyst.

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B. H. Davis et al., "Catalytic Conversion of Alcohols II. Influence of Preparation and Pretreatment on the Selectivity of Zirconia", Ind. Eng. Chem. Prod. Res. Dv., vol 18, No. 3, 1979 pp. 191-198.
M. J. Torralvo et al., "Crystallization Behaviour of Zirconium Oxide Gels", Journal of Catalysis 86(1984) pp. 473 to 476.

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