Process for the preparation of unsaturated carboxylate esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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2604109R, 558353, 560105, 560114, 560155, 560201, 560226, C07C 5114

Patent

active

046705821

ABSTRACT:
Process for the preparation of carboxylate esters of alpha-ethylenically unsaturated alcohols by reacting an ethylenically unsaturated compound with carbon monoxide and an enolizable ketone in the presence of a catalytic system formed by combining a palladium catalyst, a triarylphosphine and a protonic acid having a pK.sub.a below 1.5, except hydrohalogenic acids and carboxylic acids.

REFERENCES:
patent: 3349119 (1967-10-01), Fenton
patent: 3437676 (1969-04-01), Kutepow
patent: 3641074 (1972-02-01), Fenton
patent: 3652655 (1972-03-01), Fenton
patent: 3660439 (1972-05-01), Schell
patent: 4414409 (1983-11-01), Waller

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