Process for the preparation of tetrachloroalkanes

Details Process for the preparation of tetrachloroalkanes Process for the preparation of tetrachloroalkanes

1976-11-05

1981-01-06

Gantz, Delbert E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Halogen containing

C07C 1728

Patent

active

042436079

ABSTRACT:
An ethylenic hydrocarbon is reacted with carbon tetrachloride in the presence of an alkyl phosphite, an iron chloride and a nitrile compound. According to this process, tetrachloroalkanes having more than two carbon atoms can be obtained in high yields.

REFERENCES:
patent: 3454657 (1969-07-01), Decker et al.
patent: 3631115 (1971-12-01), Nakagawa et al.
patent: 3651019 (1972-03-01), Asscher et al.
Asahara et al., J. Japan Chem. Soc., vol. 74, pp. 703-705, (1970) (see Chem. Abs., vol. 75, 48334N (1971)).

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