Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Reexamination Certificate
2000-07-12
2001-10-09
Padmanabhan, Sreeni (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C568S721000, C568S722000, C568S723000, C568S724000, C568S725000, C568S774000, C568S779000
Reexamination Certificate
active
06300527
ABSTRACT:
OTHER COMMONLY-OWNED COPENDING APPLICATIONS
Reference is also made to other commonly-owned U.S. application Ser. Nos. 09/288,195, filed Apr. 8, 1999, 09/407,314, filed Sep. 28, 1999, and Ser. No. 09/416,855, filed Oct. 12, 1999.
TECHNICAL FIELD
This invention relates to novel, highly efficient processes for the preparation of tetrabromobisphenol-A.
BACKGROUND
Tetrabromobisphenol-A is one of the most widely used brominated flame retardants in the world. It is used extensively to provide flame retardancy for styrenic thermoplastics and for some thermoset resins.
Processes used for producing tetrabromobisphenol-A generally fall into three categories. The first category includes processes in which substantial amounts of methyl bromide are co-produced along with the tetrabromobisphenol-A. Generally, up to 40-50 pounds of methyl bromide can be expected per 100 pounds of tetrabromobisphenol-A produced. In most cases, the processes within this first category feature reacting bisphenol-A and bromine in methanol. The ring-bromination of the bisphenol-A is a substitution reaction which generates one mole of HBr per ring-bromination site. Thus, for the production of tetrabromobisphenol-A, four moles of HBr are generated per mole oftetrabromobisphenol-A produced. The HBr in turn reacts with the methanol solvent to produce the methyl bromide co-product. After the bisphenol-A and bromine feed are finished, the reactor contents are cooked for one to two hours to complete the reaction. At the end of the reaction, water is added to the reactor contents to precipitate out the desired tetrabromobisphenol-A product.
The second category of processes features the production of tetrabromobisphenol-A without the co-production of substantial amounts of methyl bromide and without the use of oxidants to convert the HBr to Br
2
. See for example U.S. Pat. No. 4,990,321; U.S. Pat. No. 5,008,469; U.S. Pat. No. 5,059,726; and U.S. Pat. No. 5,138,103. Generally, these processes brominate the bisphenol-A at a low temperature, e.g., 0 to 20° C., in the presence of a methanol solvent and a specified amount of water. The water and low temperature attenuate the production of methyl bromide by slowing the reaction between methanol and HBr. The amount of water used, however, is not so large as to cause precipitation of the tetrabromobisphenol-A from the reaction mass during the bromination reaction. Additional water for that purpose is added at the end of the reaction. This type of process typically uses a fairly long aging or cook period after the reactants have all been fed, and requires additional process time for the final precipitation of tetrabromobisphenol-A via the last water addition.
In the third category are those processes which feature the bromination ofbisphenol-A with bromine in the presence of a solvent and, optionally, an oxidant, e.g., H
2
O
2
, Cl
2
, etc. See for example U.S. Pat. No. 3,929,907; U.S. Pat. No. 4,180,684; U.S. Pat. No. 5,068,463 and Japanese 77/034620 B4 77/09/05. The solventis generally awater-immiscible halogenated organic compound. Water is used in the reaction mass to provide a two-phase system. As the bisphenol-A is brominated, the tetrabromobisphenol-A is formed in the solvent. The co-produced HBr is present in the water. When used, the oxidant oxidizes the HBr to Br
2
, which in turn is then available to brominate more bisphenol-A and its under-brominated species. By oxidizing the HBr to Br
2
, only about two moles of Br
2
feed are needed per mole of bisphenol-A fed to the reactor. To recover the tetrabromobisphenol-A from the solvent, the solution is cooled until tetrabromobisphenol-A precipitation occurs. The cooling of the solution to recover tetrabromobisphenol-A entails additional expense and process time.
Process technology for producing tetrabromobisphenol-A is described in commonly-owned U.S. Pat. Nos. 5,527,971, 5,723,690, 5,847,232, 6,002,050, 6,084,136, and 6,084,137 and in commonly-owned co-pending U.S. Patent Application Nos. 09/407,314, filed Sep. 28, 1999, 09/329,374, filed Jun. 10, 1999, and Ser. No. 09/416,855 filed Oct. 12, 1999. One of the factors involved in achieving the highly desirable results made possible by these commonly-owned processes is relatively close control of the amount of excess unreacted bromine in the liquid phase of the reaction mass during the bromination. In most cases this amount is maintained in the range of about 50 to about 10,000 ppm of unreacted bromine in the liquid phase of the reaction mass. Failure to keep the bromine level in the liquid phase of the reaction mass below this level especially when using a liquid bromine feed can have adverse repercussions, especially on the color characteristics of the tetrabromobisphenol-A product. In commonly-owned copending U.S. Pat. Nos. 6,084,136 and 6,084,137, a process is described wherein from about 50 to 20,000 ppm of unreacted bromine can be maintained in the liquid phase of the reaction mass by employing, inter alia, a feed stream of gaseous bromine to the reaction mass, if the feed stream has a Reynold's No. ≧50,000. In this way a product having improved color, e.g., an APHA color of less than about 50, and lower ionic content can be produced.
Since the commonly-owned processes referred to above involve formation of tetrabromobisphenol-A precipitate as the bromination is proceeding, such precipitate formation can render colorimetric methods for closely assessing bromine concentration in the liquid phase of the reaction mass somewhat problematical. And while feed of vaporous bromine in the manner described in U.S. Pat. Nos. 6,084,136 and 6,084,137, referred to hereinabove, permits greater latitude in the amount of excess bromine that can be tolerated in liquid phase of the reaction mass, it remains necessary to observe and maintain careful control over the character (e.g., Reynold's Number) and quantities of the vaporous bromine being fed to the reaction mass in order to ensure production of product of acceptable color characteristics.
It would thus be of considerable advantage if a way could be found of producing tetrabromobisphenol-A of desirable minimal color with process technology that is even more tolerant of the amount of unreacted bromine in the liquid phase of the reaction mixture. And it would be particularly desirable if this objective could be achieved without sacrifice of other advantageous features of the commonly-owned technology, such as forming during the bromination precipitated tetrabromobisphenol-A that is highly pure, readily recoverable, and formed in high yield based on the bisphenol-A fed to the reaction. This invention is deemed to make possible the achievement of each of the foregoing objectives.
THE INVENTION
This invention relates, inter alia, to a process for the production of tetrabromobisphenol-A by the bromination of bisphenol-A and/or underbrominated bisphenol-A, which process features: a water and water-miscible organic solvent reaction medium; a relatively high reaction temperature; and the presence, in the reaction medium, of both (i) excess unreacted Br
2
during the feed of bisphenol-A to the reactor, and (ii) sufficient HBr to protect the tetrabromobisphenol-A produced against undesirable color formation. Tetrabromobisphenol-A precipitates from the reaction mass and is easily recovered. Product of high purity (97% or more) and very low color (APHA of 50 or less) can be produced, even when using large excesses of bromine in the reaction.
The processes of this invention feature the efficient production of high-quality, low-color tetrabromobisphenol-A in high yields under operating conditions that do not require such close control of the ratio between bromine and bisphenol-A fed into and maintained in the reaction mass. Indeed, it has been found possible to produce low-color tetrabromobisphenol-A pursuant to this invention with as much as about 80,000 ppm of unreacted bromine in the liquid phase of the reaction mass. Moreover, the processes of this invention can be run in the batch mode or in the continuous mode. When run in the ba
Elnagar Hassan Y.
Harkins, Jr. Alvin E.
Holub Richard A.
Manimaran Thanikavelu
McKinnie Bonnie G.
Albemarle Corporation
Padmanabhan Sreeni
Spielman, Jr. E. E.
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