Process for the preparation of tertiary olefins and n-alkanols

Details Process for the preparation of tertiary olefins and n-alkanols Process for the preparation of tertiary olefins and n-alkanols

1981-12-02

1983-02-01

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

585639, C07C 2900, C07C 120

Patent

active

043717250

ABSTRACT:
Process for the preparation of tertiary olefins by catalytic cleavage of their n-alkyl ethers at elevated temperature and with simultaneously recovery of the corresponding n-alkanols, characterized in that the cleavage is carried out in the presence of acidic molecular sieves, which have been activated, if necessary, by a treatment with hydrogen, at temperatures of from 100.degree. to 300.degree. C.

REFERENCES:
patent: 3170000 (1965-02-01), Verdol
patent: 4006198 (1977-02-01), Tesei et al.
patent: 4025575 (1977-05-01), Chang et al.
patent: 4238631 (1980-12-01), Daviduk et al.
patent: 4306106 (1981-12-01), Kerr et al.

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