Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing
Patent
1995-06-05
1998-11-24
Nazario-Gonzalez, Porfirio
Organic compounds -- part of the class 532-570 series
Organic compounds
Heavy metal containing
556 12, 556 28, 556 43, 556 53, 556 54, 556 56, 502103, 502117, 526943, 585532, C07F 1700, C07F 700, C07C 202
Patent
active
058409483
ABSTRACT:
The invention relates to a process for the preparation of a compound of the formula IV or IVa ##STR1## in which R.sup.1 -R.sup.5 are preferably hydrogen or alkyl, which comprises reacting a compound I ##STR2## with a compound II ##STR3## in which X.sup.1 and X.sup.2 are preferably halogen, to give the corresponding indanones, which are converted into the compounds IV and IVa by reduction and dehydration. The compounds IV and IVa are important intermediate products for the preparation of chiral metallocene complexes which are suitable catalyst components for olefin polymerization.
REFERENCES:
patent: 4769510 (1988-09-01), Kaminsky et al.
patent: 4892851 (1990-01-01), Ewen et al.
patent: 4931417 (1990-06-01), Miya et al.
patent: 5017714 (1991-05-01), Welborn
patent: 5087677 (1992-02-01), Brekner et al.
patent: 5103030 (1992-04-01), Rohrmann et al.
patent: 5145819 (1992-09-01), Winter et al.
patent: 5243001 (1993-09-01), Winter et al.
patent: 5276208 (1994-01-01), Winter et al.
patent: 5296434 (1994-03-01), Karl et al.
patent: 5324800 (1994-06-01), Welborn, Jr.
patent: 5329033 (1994-07-01), Spaleck et al.
patent: 5374752 (1994-12-01), Winter et al.
patent: 5455365 (1995-10-01), Winter et al.
patent: 5455366 (1995-10-01), Rorhmann et al.
patent: 5514760 (1996-05-01), Karl et al.
patent: 5532396 (1996-07-01), Winter et al.
patent: 5561093 (1996-10-01), Fujita et al.
patent: 5670436 (1997-09-01), Herrmann et al.
Bulletin De La Societe Chimique De France, "Etude de monomeres halogenes et de leur polymerisation cationique", No. 11, pp. 3092-3095, (1973).
J. Org. Chem., "Friedel-Crafts Reactions of Ethyl Cyclopropanecarboxylate", vol. 46, pp. 3758-3760 (1981).
Soga, K. et al., Macromolecules, "Perfect Conversion of Aspecific Sites into Isopecific Sites in Ziegler-Natta Catalysts", vol. 22, pp. 3824-3826, (1989).
J. Org. Chem., "Friedel-Crafts Chemistry. A Mechanistic Study of the Reaction of 3-Chloro-4'-fluoro-2-methylpropiophenone with AlCl.sub.3 and AlCl.sub.3 -CH.sub.3 NO.sub.2 ", vol. 43, No. 16, pp. 3126-3131 (1978).
Spaleck et al., New J. Chem., "Stereorigid Metallocenes: Correlations Between Structure and Behaviour in Homopolymerizations of Propylene", vol. 14, pp. 499-403 (1990).
Roll, V.W., et al., Angew. Chem., "Stereo-und Regioselektivitat von chiralen, alkylsubstituierten ansa-Zirconocen-Katalysatoren bei der Methylalumoxan-aktivierten Propen-Polymerization", vol. 102, No. 3, pp. 339-341 (1990).
Piccoliovazzi, N. et al., Organometallics, "Electronic Effects in Homogeneous Indenylzirconium Ziegler-Natta Catalysts", vol. 9, pp. 3098-3105 (1990).
Miyamota, T.K., et al., Chemistry Letters, The Chemical Society of Japan, "A Bulky Ligand and its Organometallic Compound: Synthesis of Heptamethylidene and a Ferrocene-Type Complex, Fe(n.sup.5 -C.sub.9 Me.sub.7).sub.2 ", pp. 729-730 (1981).
Esperas, S., Acta Chemica Scandinavica, "The Crystal and Molecular Structure of Cyano(methylisocyanide)gold(I)", A 30, No. 7, pp. 527-530 (1976).
Adcock et al., Austr. J. Chem., vol. 29, "Substituent Effects by .sup.19 F Nuclear Magnetic Resonance: Polar and .pi.-Electron Effects", pp. 2571-2581.
Marechal et al., Bull. Soc. Chim. Fr. 6, "Homopolymerisation cationlique des dimethyl-4,7,dimethyl-4,6 et dimethyl-5,6 indenes", No. 348, pp. 1981-2039, (1969).
Chemical Abstracts 90:567 103691p; (1978).
Criegee et al., Chem. Ber., vol. 94, "Uber den Nickelkomplex C.sub.18 H.sub.22 Ni und den daraus gewonnenen Kohlenwasserstoff C.sub.13 H.sub.18 ", pp. 3461-3468 (1964).
Hart et al., Notes, J. Am. Chem. Soc., vol. 72, "Acylation-Alkylation Studies", pp. 3286-3287 (1950).
Katz, Thomas J., J. Am. Chem. Soc., "Asymmetric Synthesis of Helical Metallocenes", vol. 108, 1986, pp. 179-181.
Ewen, J.A., et al, J. Am. Chem. Soc., Crystal Structures and Sterospecific Propylene Polymerizations with Chiral Hafnium Metallocene Catalysts, vol. 109, 1987, pp. 6544-6545.
Kuber Frank
Rohrmann Jurgen
Nazario-Gonzalez Porfirio
Targor GmbH
LandOfFree
Process for the preparation of substituted indenes and their use does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Process for the preparation of substituted indenes and their use, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the preparation of substituted indenes and their use will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1704320