Chemistry of hydrocarbon compounds – Aromatic compound synthesis – Having alkenyl moiety – e.g. – styrene – etc.
Reexamination Certificate
2000-08-14
2002-05-28
Griffin, Walter D. (Department: 1764)
Chemistry of hydrocarbon compounds
Aromatic compound synthesis
Having alkenyl moiety, e.g., styrene, etc.
C585S435000, C585S436000, C585S469000
Reexamination Certificate
active
06395946
ABSTRACT:
The present invention relates to a process for the preparation of styrene or substituted styrenes, more specifically to such a process comprising the gas phase dehydration of 1-phenyl ethanol or substituted 1-phenyl ethanols.
Within the further context of the present application the term “substituted styrenes” refers to vinyl aromatic compounds of the general formula
Ar—CR═CH
2
,
wherein Ar is a phenyl, tolyl or xylyl group and R is H or a methyl group. When referring to “styrene” in the present application, these substituted styrenes are also included, unless indicated otherwise. Similarly, the term “substituted 1-phenyl ethanols” refers to aromatic alcohols of the general formula
Ar—C(R)(CH
3
)—OH
wherein Ar and R are as defined above. When referring to “1-phenyl ethanol”, these substituted 1-phenyl ethanols are also included, unless indicated otherwise.
A commonly known method for manufacturing styrene is the coproduction of propylene oxide and styrene starting from ethylbenzene (a Styrene Monomer/Propylene Oxide or SM/PO process). In general such process involves the steps of (i) reacting ethylbenzene with oxygen or air to form ethylbenzene hydroperoxide, (ii) reacting the ethylbenzene hydroperoxide thus obtained with propene in the presence of an epoxidation catalyst to yield propylene oxide and 1-phenyl ethanol, and (iii) converting the 1-phenyl ethanol into styrene by dehydration using a suitable dehydration catalyst. The present invention particularly focuses on the last step, i.e. the dehydration of 1-phenyl ethanol to yield styrene.
Step (iii) of the process described above, i.e. the production of styrene by dehydrating 1-phenyl ethanol, can be carried out in different ways as is well known in the art. In general, the dehydration can be carried out in the gas phase or in the liquid phase in the presence of a dehydration catalyst. Suitable dehydration catalysts are known and include for instance acidic materials like alumina, alkali alumina, aluminium silicates and H-type synthetic zeolites. Dehydration conditions are also well known and usually include reaction temperatures of 50-205° C., typically 100-200° C., for liquid phase dehydration and 210-320° C., typically 280-310° C., for gas phase dehydration. Pressures usually range from 0.1 to 10 bar.
In GB-A-2,176,801 the liquid-phase dehydration of an aromatic alcohol into an aromatic vinyl compound is described, wherein the dehydration is carried out at elevated temperature in the presence of a solid acid catalyst. Aluminium silicate and H-type synthetic zeolites are mentioned as suitable catalysts, but no further details as to the properties of these materials is given.
In Takahashi et al., The Canadian Journal of Chemical Engineering, Sol. 66, June 1988, pp. 433-437, a process for the liquid phase dehydration of 1-phenyl ethanol into styrene is described using various types of acidic catalysts. The catalysts used include silica-alumina, Y type zeolites, mordenites, H-ZSM-5 and several aluminas, all used in the form of crushed particles of 24-32 mesh (corresponding with 0.5 to 0.7 mm). This publication concludes that when the concentration of effective acid sites on the catalyst increases, the dehydration reaction rate increases, but the styrene selectivity decreases. A certain alumina catalyst was found to provide the best balance between reaction rate and styrene selectivity.
In JP-A-61/72727 the gas-phase dehydration of 1-phenyl ethanol into styrene is described, wherein a zeolite is used as the dehydration catalyst. The patent application does not give any further details as to the types and properties of suitable zeolites, except that in the working examples OSZ-250, a H-Y-type zeolite, is used in the form of crushed particles having a size of 32-60 mesh (corresponding with 0.25-0.50 mm). In the working example the feed solely consisted of 1-phenyl ethanol without other compounds being present.
The present invention aims to provide an effective dehydration process for converting 1-phenyl ethanol into styrene, which process can also be used in the dehydration step of a commercial SM/PO process. In such a process the feed to the dehydration section will not only contain 1-phenyl ethanol, but also substantial amounts of other compounds formed in the preceding sections. Examples of such compounds are 2-phenyl ethanol, methyl phenyl ketone, some styrene monomer, ethylbenzene and water.
It has been found that 1-phenyl ethanol either as such or in a process stream in an SM/PO process can be very effectively converted into styrene in a gas phase dehydration process by selecting a zeolitic catalyst meeting certain specific requirements.
Accordingly, the present invention relates to a process for the preparation of styrene or substituted styrenes comprising the gas phase dehydration of 1-phenyl ethanol or substituted 1-phenyl ethanol in the presence of a solid acidic catalyst comprising a zeolite and a binder material, wherein weight ratio of zeolite to binder is in the range of from 1:99 to 90:10 and wherein the following relation applies:
0<K<5 (1)
with:
K=V/S*[(Pz*fz)+(Pb*fb)]
½
(2)
wherein:
V/S is the volume/surface ratio of the catalyst used in mm;
fz is the weight fraction of zeolite present in the catalyst in grams zeolite per gram catalyst;
fb is the weight fraction of binder present in the catalyst in grams binder per gram catalyst;
Pz is the intrinsic productivity of the zeolite expressed as grams styrene produced per gram of zeolite per hour, as measured for pure zeolite samples of small particle size (i.e. <0.1 mm) at the temperature applied in gas phase dehydration and at a conversion of 1-phenyl ethanol into styrene below 80%; and
Pb is the intrinsic productivity of the binder expressed as grams styrene produced per gram of binder per hour, as measured for pure binder samples of small particle size (i.e. <0.1 mm) under the same conditions as used for determining Pz.
The catalyst to be used comprises zeolite and binder in a weight ratio of zeolite to binder of from 1:99 to 90:10, preferably of from 3:97 to 35:65. Suitable binder materials include inorganic oxides like silica, alumina, boria, zirconia, titania and silica-alumina as well as organic materials like carbon or polymers. Of these, the substantially inert binder materials silica and alumina are preferred. The zeolite to be used in principle may be any zeolite having sufficient acidity to catalyse the dehydration of 1-phenyl ethanol. Suitable zeolites, then, include H-ZSM-5, H-ZSM-23, H-mordenite, H-Y-zeolite and beta-zeolite, but also silica-alumina phosphate molecular sieve materials, such as SAPO-34. However, other acidic zeolitic materials may be applied as well.
The catalyst to be used must meet very specific requirements as regards particle size, outer surface and zeolite content. These requirements are summarised in equations (1) and (2):
0<K<5 (1)
with:
K=V/S*[(Pz*fz)+(Pb*fb)]
½
(2)
wherein V/S, Pz, Pb, fz and fb have the meaning as indicated above. The quotient of volume V (in mm
3
) and outer surface S (in mm
2
) is expressed in mm and is a measure for the particle size and its shape. For spherical catalyst particles, V/S is ⅙ of the particle diameter. For cylindrical catalyst particles V/S is ¼ of the particle diameter. For catalyst particles shaped as trilobes, stars, quadrulobes, wokkels and the like, the ratio V/S will be smaller than ¼ of the outer diameter of the enclosing cylinder. It has been found advantageous to select V/S, Pz, Fb, fz and fb such that K has a value of less than 2, preferably of less than 0.5 and most preferably of less than 0.2.
The weight fractions of zeolite (fz) and binder (fb) Indicate the amounts of zeolite and binder in grams per gram of catalyst. The sum of fz and fb is equal to 1, i.e. the catalyst consists of zeolite and binder. The productivities Pz and Pb in fact indicate the dehydration activity of the pure zeolite and pure binder, respectively. For the pu
Lange Jean-Paul
Mesters Carolus Matthias Anna Maria
Van Giezen Joseph Cornelis
Griffin Walter D.
Shell Oil Company
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