Process for the preparation of spherical amorphous silicon nitri

Chemistry of inorganic compounds – Silicon or compound thereof – Binary compound

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501 97, C01B 21068

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052366847

ABSTRACT:
To prepare spherical amorphous silicon nitride (Si.sub.3 N.sub.4), a silicon halide and ammonia are reacted in the vapor phase in the absence of water or water vapor in a vertically arranged reaction container, a silicon halide/ammonia reaction product being formed. In this reaction, a silicon halide/inert gas mixture is passed into the lower part of the reaction container and ammonia is passed into its upper part, the ratio of SiHal.sub.4 :NH.sub.3 being 1:(5.8 to 6.6). By establishing a stationary state, the reaction takes place only in the central part of the reaction container. After the silicon halide/ammonia reaction product has been removed from the reaction container, it is heated to temperatures of 950.degree. to 1150.degree. C. in an atmosphere containing ammonia.

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patent: 4929432 (1990-05-01), Shen
Patent Abstracts of Japan, vol. 13, No. 315 [3663], 1989.
Patent Abstracts of Japan, vol. 14, No. 382 [4325], 1990.

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