Process for the preparation of selectively halogenated ketones a

Details Process for the preparation of selectively halogenated ketones a Process for the preparation of selectively halogenated ketones a

1975-08-01

1977-03-22

Thomas, Jr., James O.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07C 4500, C07C 4916

Patent

active

040137228

ABSTRACT:
A method is disclosed wherein selectively halogenated ketals and ultimately, halogenated ketones are prepared by treating secondary ethers with halogen in an organic solvent under conditions of ordinary temperature and pressure. This method obviates the need for extreme times, temperatures, and complex equipment.

REFERENCES:
patent: 3919328 (1975-11-01), Gutierrez et al.
Loewenthal et al., Protective Groups in Organic Chemistry, Plenum Press, pp. 330-331 (1973).
House, Modern Synthetic Reactions, 2nd Edition, pp. 407-471.

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