Process for the preparation of selectively halogenated ketones a

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260338, 2603406, 2603407, 2603409, 260590C, 260591, 260592, 260593H, 260611R, 260612R, 260612D, 260615A, C07C 4110, C07C 4500

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039858081

ABSTRACT:
A method is disclosed wherein selectively halogenated ketals, and ultimately, halogenated ketones are prepared by treating secondary alcohols or halohydrins with halogen in an organic solvent under conditions of ordinary temperature and pressure. This method obviates the need for extreme times, temperatures and complex equipment while resulting in higher yields than obtained heretofore.

REFERENCES:
patent: 3453290 (1969-07-01), Propper
patent: 3824292 (1974-07-01), Kirby
"The Chem. of the Carbonyl Group," Patai, Editor, pp. 188-191, 207-210, (1966), John Wiley and Sons.

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