Process for the preparation of ruthenium complexes and their in

Details Process for the preparation of ruthenium complexes and their in Process for the preparation of ruthenium complexes and their in

1995-01-31

1996-09-24

Beck, Shrive

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 21, 556136, 556137, 502155, 502162, C07F 950, B01J 3124

Patent

active

055592627

ABSTRACT:
This invention relates to a process of preparing a ruthenium complex of the formula RuH.sub.2 (PR.sub.3).sub.2 L.sub.2 wherein PR.sub.3 is an organophosphoms ligand and L is H.sub.2 or PR.sub.3 ; a catalyst comprising at least one ruthenium complex having the formula RuH.sub.2 (PR.sub.3)L.sup.1.sub.3 wherein L.sup.1 is a neutral electron pair donor ligand; a process for preparing the catalyst and its use in situ in the hydrogenation of nitriles.

REFERENCES:
patent: 3454644 (1969-07-01), Dewhirst
patent: 3538133 (1970-11-01), Knoth
patent: 3804914 (1974-04-01), Fahey
patent: 3957827 (1976-05-01), Lyons
patent: 4362671 (1982-12-01), Diamond et al.
patent: 5324850 (1994-06-01), Juge et al.
patent: 5426216 (1995-06-01), Genet et al.
Chaudret et al., Organometallics, 4, p. 1722 (1985). (month unknown).
Genet, J. P. et al, Tet. Assym., 2, 43 (1991) (month unknown).
Cooke, M. et al, J. Chem. Soc. (A), p. 16 (1971) (month unknown).
Powell, J. et al, J. Chem. Soc. (A), 159 (1968) (month unknown).
Chaudret, B. et al, J. Am. Chem. Soc., 113, 2314 (1991) (month unknown).
Christ, M. L. et al, Organometallics 13, 3800-3804 (1994) (month unknown).
Armit, P. W. et al, J. Chem. Soc., Dalton Transactions, pp. 1663-1672 (1975) (month unknown).
Joshi, A. M. et al, Inorg, Chim. Acta, 198-200, 283-296 (1992) (month unknown).
Albers, M. O. et al, Inorganic Syntheses, 26, 68 (1989) (month unknown).
Joshi, A. M. et al, Prog. in Catal., 73, 143 (1992) (month unknown).
Suarez, T. et al, J. Mol. Cat., 45, 335 (1988) (month unknown).
Yoshida, T. et al, J.C.S. Chem. Comm., 870 (1979) (month unknown).

Affiliated with

Also associated with

Rating

Process for the preparation of ruthenium complexes and their in does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for the preparation of ruthenium complexes and their in , we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the preparation of ruthenium complexes and their in will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1929731