Chemistry: fischer-tropsch processes; or purification or recover – Plural zones each having a fischer-tropsch reaction
Reexamination Certificate
2011-03-22
2011-03-22
Parsa, Jafar (Department: 1621)
Chemistry: fischer-tropsch processes; or purification or recover
Plural zones each having a fischer-tropsch reaction
C518S700000, C518S705000
Reexamination Certificate
active
07910630
ABSTRACT:
Process for the preparation of dimethyl ether product by catalytic conversion of synthesis gas to dimethyl ether comprising the steps of contacting a stream of synthesis gas comprising carbon dioxide in a dimethyl ether synthesis step in one or more reactors and with one or more catalysts being active in formation of methanol and dehydration of methanol to dimethyl ether, to form a product mixture comprising the dimethyl ether and carbon dioxide, washing the product mixture in a scrubbing zone with a liquid solvent being rich in dialkyl ether of a polyalkylene glycol and thereby dissolving carbon dioxide and dimethyl ether in the liquid solvent, treating the liquid solvent being withdrawn from the scrubbing zone sequentially in separation zone to effect desorption of the dissolved carbon dioxide and to recover a substantially pure dimethyl ether product and the liquid solvent in its substantially lean form and recycling the lean liquid solvent to the scrubbing zone.
REFERENCES:
patent: 5908963 (1999-06-01), Voss et al.
patent: 6458856 (2002-10-01), Peng et al.
patent: 1102943 (1968-02-01), None
Greene et al., carbon dioxide removal and recovery—new polyglocol ether processes, (Proceedings of the gas conditionings conference (1995) 1H-21H.
Hernandez et al., solvent unit cleans synthesis gas, (chemical engineering (New York, NY, United States) (1989), 62 (2), 154-156.
Madsen Jørgen
Rostrup-Nielsen Thomas
Dickstein & Shapiro LLP
Haldor Topse A/S
Parsa Jafar
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