Process for the preparation of pure alkyl tert-alkyl ethers and

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568699, C07C 4105, C07C 4136

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045046883

ABSTRACT:
A process for the preparation of pure alkyl tertiary alkyl ethers and hydrocarbon raffinates which are substantially free from tertiary olefins and alkanols. An alkanol and a hydrocarbon mixture containing at least one tertiary olefin are contacted with the alkanol being present in a stoichiometric excess. The reaction product is removed from the reaction zone and excess alkanol in the reaction product or a partial stream thereof is absorbed on a synthetic ion exchanger containing groups which exchange cations or anions or mixtures of such ion exchangers. After absorption of at least a portion of the alkanol on the synthetic ion exchanger, the alkanol is desorbed by contacting the same with a hydrocarbon mixture containing at least one tertiary olefin.

REFERENCES:
patent: 3021274 (1962-02-01), Radzitzky
patent: 3726942 (1973-04-01), Louder
patent: 4322565 (1982-03-01), Dotson et al.
patent: 4371718 (1983-02-01), Hutson, Jr.

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