Process for the preparation of polyolefin waxes

Chemistry of hydrocarbon compounds – Product blend – e.g. – composition – etc. – or blending process... – Component of indefinite molecular weight greater than 150

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585 10, 585 18, 585512, 585946, 526153, 526162, C10L 116

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active

057508135

ABSTRACT:
A process for the preparation of a polyolefin wax by polymerization or copolymerization of olefins or diolefins in suspension and in the presence of a catalyst. The process utilizes a metallocene and a cocatalyst, wherein the metallocene is a compound of the formula I ##STR1## in which M.sup.1 is a metal of group IVb, Vb or VIb of the Periodic Table of Elements, R.sup.1 and R.sup.2 are identical or different and are a hydrogen atom, a C.sub.1 -C.sub.10 -alkyl group, a C.sub.1 -C.sub.10 -alkoxy group, a C.sub.6 -C.sub.10 -aryl group, a C.sub.6 -C.sub.10 -aryloxy group, a C.sub.2 -C.sub.10 -alkenyl group, a C.sub.7 -C.sub.40 -arylalkyl group, a C.sub.7 -C.sub.40 -alkylaryl group, a C.sub.8 -C.sub.40 -arylalkenyl group or a halogen atom and R.sup.3 and R.sup.4 are identical or different and are a mononuclear or polynuclear hydrocarbon radical which may form a sandwich structure with the central atom M.sup.1, low-boiling hydrocarbons having 3 or 4 carbon atoms or low-boiling halogenated hydrocarbons are used as suspending agents and the heat of reaction is removed by evaporative cooling.

REFERENCES:
patent: 3951935 (1976-04-01), Engelmann
patent: 4754007 (1988-06-01), Pullukat
patent: 4962248 (1990-10-01), Winter et al.
patent: 4962262 (1990-10-01), Winter
patent: 5023388 (1991-06-01), Luker et al.
patent: 5304614 (1994-04-01), Winter et al.
European Search Report 93 10 8106, May 18, 1994.

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