Process for the preparation of polymers from polymer slurries

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Treating polymer containing material or treating a solid...

Reexamination Certificate

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C210S665000, C422S186220, C422S198000

Reexamination Certificate

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11056712

ABSTRACT:
A process for manufacturing a polymer having a molecular weight in excess of 5,000, and preferably in excess of 40,000, comprises, producing a polymerized reaction mass in which the polymer is dispersed, the reaction mass including solvent(s), unreacted monomer and other unwanted contaminants; feeding the reaction mass to a means for disentangling the polymer's molecules to produce a modified polymer in the reaction mass; feeding the modified polymer in the reaction mass to a polymer-recovering means; removing the unwanted volatiles and other byproducts; and, recovering a high molecular weight substantially pure modified polymer having substantially the same molecular weight as the polymer fed to the disentangling means and a viscosity at least 10% lower than that of the polymer fed to the disentangling means.

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J.D. Ferry's “Viscoelastic Properties of Polymers”, 2nd Ed., Wiley, Chapter 17—“Concentrated Solutions, Plasticized Polymers and Gels” (1989).
“Chain Dynamics in Entangled Polymers: Diffusion versus Rhelogy & Their Comparison”, by S.Q. Wang, J. Polymer Science, Part B, vol. 41 1589 (2003).
“The Entanglement Concept in Polymer Rheology”, W.W. Graessley, Advances in Polymer Science, vol. 16, Table 5.2, p. 55, Springer-Verlag (1974).
“Polymer Extrusion” by Chris Rauwendal, Hanser Publishing (1986), pp. 154-163.

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