Process for the preparation of polycarboranylphosphazenes

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From boron reactant having at least one boron to hydrogen or...

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528168, 528399, 528 6, C08G 7300

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active

042764033

ABSTRACT:
Polydihalophosphazenes, e.g. --N.dbd.P(Cl).sub.2 ].sub.n, are allowed to react at ambient temperatures for at least one hour with a lithium carborane in a suitable inert solvent. The remaining chlorine substituents of the carboranyl polyphosphazene are then replaced with aryloxy or alkoxy groups to enhance moisture resistance. The polymers give a high char yield when exposed to extreme heat and flame and can be used as insulation.

REFERENCES:
patent: 3155630 (1964-11-01), Schroeder
patent: 3164556 (1965-01-01), Apley et al.
patent: 3169933 (1965-02-01), Liu et al.
patent: 3549604 (1970-12-01), Semenuk et al.

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