Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1975-12-15
1977-11-08
Thomas, Jr., James O.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260597R, C07C 4502
Patent
active
040575837
ABSTRACT:
The invention provides a novel synthesis for pinacolone comprising reacting 2-methyl-but-2-ene and/or 2-methyl-but-1-ene with an aqueous inorganic acid, adding formaldehyde gradually at a temperature between 50.degree. and 200.degree. C at a rate of 0.5 - 1.5 moles of formaldehyde per mole of butene compound, allowing the mixture to react further, and separating the pinacolone by distillation.
REFERENCES:
Nishimura et al., Chem. Abst., vol. 67, 73569K, (1967).
Hickihbottom, Reactions of Organic Compounds, pp. 33-34, (1957).
Nishimura et al., Chem. Abst., vol. 66, 37075S, (1960).
Merz Walter
Nachtsheim Dieter
Bayer Aktiengesellschaft
Reamer James H.
Thomas, Jr. James O.
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