Process for the preparation of phenylhydroquinone

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3912, C07C 3706

Patent

active

052103307

ABSTRACT:
Disclosed is an improved process for the preparation of phenylhydroquinone wherein hydroquinone is first alkylated with cyclohexene to produce cyclohexylhydroquinone which is then dehydrogenated to obtain phenylhydroquinone. The improvement comprises carrying out both the alkylation and dehydrogenation reactions in the presence of a solvent comprising diphenyl ether, biphenyl or a mixture thereof. The solvent possesses selective solubility for hydroquinone and cyclohexylhydroquinone which permits the separation of unreacted hydroquinone from the alkylation reaction product. The boiling point of the solvent also permits the dehydrogenation reaction to be performed at substantially atmospheric pressure.

REFERENCES:
patent: 4798911 (1989-01-01), Lentz et al.
patent: 4847429 (1989-07-01), Fuller et al.

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