Process for the preparation of phenol

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S716000

Reexamination Certificate

active

07868210

ABSTRACT:
A process is described for the preparation of phenol by the hydrodeoxygenation of polyhydroxylated benzene derivatives or by the selective hydroxylation of benzene under depletive conditions, characterized in that the above-mentioned reactions are carried out in the presence of a catalyst based on multi component metal oxides comprising at least one metal selected from the groups VB, VIB, VIII, IB, IIB, IVA, VA.

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Jelinek, et al., “Partial dehydroxylation of pyrocatechol and mixtures of dihydric phenols under pressure”, Chemicky Prumysl, XP002271913, 1956. (Abstract only).
Matthias, “Konventionelle und Kombinatorische Suche nach neuen Katalysatoren fuer die selektrive Oxidation von Benzol zu Phenol”, Einleitung und Problemstellung, pp. 1-140, XP002343627, 2000.
Yamanaka, et al., “Direct Synthesis of Phenol from Benzene with O2over Vmo-Oxide/SiO2Catalyst”, Studies in Surface Science and Catalysis, vol. 130, pp. 809-814, XP008052138, 2000.
Emig, et al., “New reaction engineering concepts for selective oxidation reactions”, Topics in Catalysis, vol. 21, No. 1-3, pp. 11-24,618 XP002343628, 2002.

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