Process for the preparation of perhaloalkylthioethers

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546276, 548376, 548378, 568 38, 568 56, 568 59, C07D23114, C07C 4916

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050829459

ABSTRACT:
The present invention relates to a process for the preparation of perhaloalkylthioethers by bringing a perhaloalkyl halide, preferably a bromide or an iodide, into contact with a disulphide in the presence of zinc and of sulphur dioxide or of a dithionite or of a hydroxymethanesulphinate or of a formate anion and sulphur dioxide.

REFERENCES:
patent: 3506718 (1970-04-01), Mutsch
Reid, Organic Chemistry of Bivalent Sulfur, vol. III, Chapter 7, 1960, pp. 362-386.

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