Process for the preparation of perhaloalkanesulfinic and -sulfon

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556119, 562113, 562125, 562829, 562834, C07C14500, C07F 108, C07F 306

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048661902

ABSTRACT:
A process for the preparation of perhaloalkanesulfinic and -sulfonic acids and derivatives of these acids. A perhaloalkanesulfinic acid salt is prepared by contacting a metal hydroxymethanesulfinate (preferably, a sodium, zinc or copper hydroxymethanesulfinate) with a perhaloalkyl halide group, in a polar solvent. Optionally, the perhaloalkanesulfinic acid salt is then converted to a perhaloalkanesulfinic or -sulfonic acid or a derivative of either of these acids.

REFERENCES:
patent: 2732398 (1956-01-01), Brice et al.
patent: 4221734 (1980-09-01), Commeyras et al.

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