Process for the preparation of perfluorocarboxylic acids

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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562541, 562605, C07C 5116

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active

047510277

ABSTRACT:
A process is described for the preparation of perfluorocarboxylic acids by oxidizing perfluoroalkylalkenes with permanganate in aqueous solution, catalytic amounts of at least one quaternary ammonium salt containing alkyl and/or arylalkyl groups being added. It is possible by these means to prepare even perfluorocarboxylic acids having a fairly long chain in a high state of purity in a readily controllable reaction and in a good space-time yield.

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patent: 4321209 (1982-03-01), Chan et al.
patent: 4346235 (1982-08-01), Sonoda et al.
patent: 4400325 (1983-08-01), von Werner et al.
Chemical Abstracts, vol. 70, (1969), Abstract No. 77334q, (Abstract of Japanese Publ. Appl. 68-29129).
Journal of Fluorine Chemistry, 13, (1979), 175-177.
Journal of Fluorine Chemistry, 17, (1981), 423-439.

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