Process for the preparation of oxiranes

Details Process for the preparation of oxiranes Process for the preparation of oxiranes

1987-01-27

1989-12-12

Hollrah, Glennon H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30102

Patent

active

048868922

ABSTRACT:
A process for the preparation of oxiranes is disclosed in which a ketone of the formula ##STR1## wherein Y represents chlorine or phenyl, X represents oxygen or CH.sub.2 and Z represents hydrogen or halogen is reacted with trimethylsulphonium methyl sulphate formed by treating dimethyl sulphide with dimethyl sulphate. The process is carried out in the presence of potassium hydroxide or sodium hydroxide powder in an inert organic diluent at 0.degree. to 60.degree. C. The products are useful as intermediates for the formation of plant growth regulants and fungicides.

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