Process for the preparation of organotin trihalides

Details Process for the preparation of organotin trihalides Process for the preparation of organotin trihalides

1977-05-03

1978-08-08

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07F 722

Patent

active

041056841

ABSTRACT:
Organotin trihalides are prepared by reacting in a polar solvent a stannous halide, hydrogen halide and an olefin of the formula ##STR1## where R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are an alkyl group, an oxygen-containing hydrocarbon group or a hydrogen atom and at least one of the groups contains a carbonyl group adjacent to the carbon-carbon double bond. The resulting product may be converted into organotin stabilizers for polyvinyl chloride and other polymers.

REFERENCES:
patent: 2731482 (1956-01-01), Stefl
patent: 3607893 (1971-09-01), Reifenberg et al.
patent: 3657294 (1972-04-01), Gloskey
patent: 3705919 (1972-12-01), Heck
Kagaku (Kyoto) 26 137-141 (1971).
J. Organometallic Chem. 25, 101-109 (1970).
Sawyer, Organotin Compounds, Marcel Dekkr, Inc. N.Y. V2, pp. 261, 374, 375, 410, 411 (1971).

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