Chemistry: fischer-tropsch processes; or purification or recover – With preliminary reaction to form hydrogen or a carbon oxide – Water utilized in the preliminary reaction
Patent
1982-05-24
1984-04-17
Mars, Howard T.
Chemistry: fischer-tropsch processes; or purification or recover
With preliminary reaction to form hydrogen or a carbon oxide
Water utilized in the preliminary reaction
518707, 518706, C07C 104, C07C 2706
Patent
active
044435614
ABSTRACT:
In a two-stage process for the conversion of H.sub.2 -poor syngas into hydrocarbons and oxygenates in which uncoverted syngas from the first stage product is converted in a second stage into paraffins over a Ni, Co or Ru catalyst, the H.sub.2 /CO molar ratio of the feed for the second stage is adjusted to the required value of 1.75-2.25 by blending this feed with an H.sub.2 -rich syngas with an H.sub.2 /CO molar ratio of at least above 1.75 which latter gas has been obtained by subjecting a small portion of the feed for the first stage to a high temperature (above 325.degree. C.) CO-shift.
REFERENCES:
patent: 4338089 (1982-07-01), Shaper et al.
Boelema Sikko J. A.
Post Martin F. M.
Sie Swan T.
Duncan John M.
Mars Howard T.
Shell Oil Company
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