Process for the preparation of naphthacenes

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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585 26, 585416, 585408, 585469, C07C 132

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048555207

ABSTRACT:
A process for the preparation of a substituted naphthacene is disclosed wherein a 1,3-diphenylpropargyl alcohol is reacted with an alkanesulfonyl halide, the resultant reaction product is heated in the presence of a hindered amine base and the resultant substituted naphthacene is recovered.

REFERENCES:
Moureu et al., C. R. Acad. Sci. (1926), vol. 182, 1440.
Moureu et al., Bull. Soc. Chem. (1930), 216.
Rigaudu et al., Tetrahedron (1977), vol. 33, 767.
Wittig et al., J. Fur Praktische Chemie N. F. (1942), vol. 160, 242.

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